Styrene-PEG (600) DMA Crosslinked Polymers for Absorption of Oil Derivatives


Kasgoz H., Heydarova S.

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, vol.48, no.7, pp.556-561, 2011 (SCI-Expanded) identifier identifier

Abstract

In this work, styrene (St) based crosslinked polymers were prepared for removal of oil derivatives from aqueous solutions. Polyethylene glycol (600) dimethacrylate (PEG (600) DMA) was used as crosslinker in synthesis of styrene based crosslinked polymers, for the first time. The polymers were characterized by FTIR, SEM, elemental analysis and solvent (toluene, chloroform and fuel-oil) absorption capacities. The effects of different reaction parameters like crosslinker type, diluents amount and the presence of pore forming agent on the absorption properties of polymers were investigated. The polymers synthesized by using PEG (600) DMA have higher solvent absorption capacity than that of synthesized by using conventional crosslinker. Furthermore, the polymers synthesized in the presence of good diluents have higher absorption capacities. The addition of pore forming agent into the reaction medium has also improved the absorption rate of polymers. The absorption capacity of polymers in different solvents is in order of chloroform toluene fuel-oil. It was seen that oil derivatives can be removed efficiently from water by the St-PEG (600) DMA polymers.