KINETICS OF A NITROUS-OXIDE CARBON-MONOXIDE INTERACTION ON POLYCRYSTALLINE PLATINUM, PALLADIUM AND RHODIUM FOILS AT LOW-PRESSURES

HAHN, T; LINTZ, HG; OMAY, IYE; ZAMBRANAMONTAN, E

doi:10.1524/zpch.1994.186.part_2.195

KINETICS OF A NITROUS-OXIDE CARBON-MONOXIDE INTERACTION ON POLYCRYSTALLINE PLATINUM, PALLADIUM AND RHODIUM FOILS AT LOW-PRESSURES

HAHN T., LINTZ H., OMAY I., ZAMBRANAMONTAN E.

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, cilt.186, ss.195-213, 1994 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 186
Basım Tarihi: 1994
Doi Numarası: 10.1524/zpch.1994.186.part_2.195
Dergi Adı: ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, INSPEC
Sayfa Sayıları: ss.195-213
İstanbul Üniversitesi Adresli: Hayır

Özet

The reduction of N2O by CO on polycrystalline foils of Pt, Pd and Rh was studied in the range 10(-6) less-than-or-equal-to p(i)/mbar less-than-or-equal-to 10(-3) and 250 less-than-or-equal-to theta/degrees-C less-than-or-equal-to 600. It is inhibited by CO at temperatures lower than 300-degrees-C. Additionally, isothermal oscillations of the reaction rate were observed on Rh at temperatures below 320-degrees-C. Above 450-degrees-C the reaction rate on Pt and Pd is independent of CO pressure and first order with respect to N2O. On Rh the reaction is first order with respect to the compound the pressure of which is less. The reaction between CO and O-2 is favoured for all catalysts, temperatures and compositions if oxygen is present in the system.